Summary Sheet #8: The Oxidation Ladder
Following up on this post, here’s an attempt at trying to put many of the reactions in organic chemistry in perspective, from the standpoint of
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Hydrates, Hemiacetals, and Acetals – Their Formation From Aldehydes/Ketones, And Mechanisms That Are As Easy As P-A-D-P-E-A-D Hydrates, hemiacetals and acetals are the products of
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Zed Shaw teaches a course in writing Python called “Python the Hard Way“. Because the hard way is easier, he says. In the end, he’s
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Once you get a handle on oxidations and reductions, you might start to notice that with some molecules these reactions can proceed in sequences. For
Read moreReagent Friday: Lithium Di-isopropyl Amide (LDA)
Lithium Diisopropyl Amide (LDA), A Strong, Sterically Hindered Base In a blatant plug for the Reagent Guide, each Friday I profile a different reagent that is
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SOCl2 Mechanism With Alcohols, With And Without Pyridine: Nucleophilic Substitution (SN2) Versus Nucleophilic Substitution With Internal Return (SNi) Most of the time, the reaction of
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Sodium Amide (Sodamide, NaNH2), A Strong Base For The Deprotonation Of Terminal Alkynes (Among Other Uses) In a blatant plug for the Reagent Guide, each Friday
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The Alcohol Reaction Map Having now finished (at long last) covering the key reactions of alcohols, let’s stop to put everything in perspective. Over the
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Steric Hindrance In Nucleophilic Substitution Reactions Sportswriter Todd Gallagher asked a question that every hockey fan has probably asked at one point. “Could a morbidly
Read moreExploring Resonance: Pi-Donation
Resonance In Organic Chemistry: Pi Donation and Pi Donors You’d think after five or six posts on resonance, that would be enough. But NO, friends,
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