Hydrohalogenation of Alkynes
…10.1021/ja00040a077 The short length of this JACS communication belies the difficulty of this experimental work! This paper describes an X-ray structure of the addition complex between HCl and an alkyne,…
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Hydration and Oxymercuration of Alkynes
…Also Be “Hydrated” via Oxymercuration (HgSO4/H2O) Hydroboration Of Alkynes (R2BH) Occurs With Anti-Markovnikov Selectivity, Giving Aldehydes From Terminal Alkynes Beware: Depending On The Alkyne, Mixtures Of Products Can Be Obtained…
Read morePartial Reduction of Alkynes With Na/NH3 To Obtain Trans Alkenes
…it, we should control it. Here’s another example. Try drawing the product of these two reactions: Click to Flip Final example. Draw the product! Click to Flip These are examples…
Read moreSuccess Stories: How Stu Aced Organic Chemistry
…every exam. This included conceptual, technical, and cognitive mistakes. For example, I did horrible on my first exam, considering the amount of time I invested in it. I wasn’t lacking…
Read moreAlkyne Hydroboration With “R2BH”
…hydroboration of alkynes, and it often appears in class notes and exams, in practice it’s more common to use dialkylboranes (R2BH) for hydroboration of alkynes. In a dialkylborane, two of…
Read moreHydrohalogenation of Alkenes and Markovnikov’s Rule
…to Flip Can you work backwards to come up with the best starting material for this reaction? Click to Flip 3. Stereoselectivity (Or Lack Thereof) In Addition of HX To…
Read moreTransesterification promoted by alkoxides
…to this page, plus over 2500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-World Example: Org….
Read moreAllylic Bromination
…completion of Propagation Step #1.[Note 3].This keeps the concentration of Br2 low and allows the free-radical reaction to out-compete the alkene addition reaction. In all other respects the allylic…
Read moreBonus Topic: Allylic Rearrangements
…There is an example of an ‘allylic rearrangement’ here – Prof. Kharasch shows that reaction of 3-bromo-1-butene with HBr under free-radical conditions (peroxides) can give 1,3-dibromobutane. This would be obtained…
Read moreOrganic Chemistry For the MCAT
…demonstrate the ability to think independently and to reason critically. As a result the MCAT examination does more than simply test an examinee’s knowledge of a particular subject. One should…
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