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Introduction to Free Radical Substitution Reactions

…safety conscious, and 3) a little crazy, fluorine gas is something you should never, ever work with. [youtube]http://www.youtube.com/watch?v=vtWp45Eewtw[/youtube]   Next Post In The Series: Introduction To Oxidative Cleavage Reactions  …

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Electrocyclic Reactions

…year was 1905. Chemist Richard Willstätter and his collaborator Wolfgang von Schmaedel were heating a reaction mixture in their laboratory at the University of Munich. They were performing a fairly…

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Bredt’s Rule (And Summary of Cycloalkanes)

communication (Ref #4) provides more details on the synthesis and reactivity of the ‘Anti-Bredt’ olefin, bicyclo[3.3.1]non-1-ene. Bredt Compounds and the Bredt Rule Dr. Gert Köbrich Angew. Chem. Int. Ed. 1973,…

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Diazomethane (CH2N2)

…on carbon to give H3C-N2(+). This is an example of a diazonium compound, which you may have encountered if you’ve covered the Sandmeyer and related reactions. Like most diazonium compounds,…

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Thionyl Chloride (SOCl2)

…Problems Once this reaction is in your synthetic toolbox, it opens up solutions to a wide range of solutions to synthesis problems. See if you can come up with two-step…

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