…such that a set of 4, 6, or “n” pi molecular orbitals is formed. [See: Conjugation and Resonance]. Since each pi-bond is comprised of two adjacent p orbitals, a molecule…
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…safety conscious, and 3) a little crazy, fluorine gas is something you should never, ever work with. [youtube]http://www.youtube.com/watch?v=vtWp45Eewtw[/youtube] Next Post In The Series: Introduction To Oxidative Cleavage Reactions …
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…communication (Ref #4) provides more details on the synthesis and reactivity of the ‘Anti-Bredt’ olefin, bicyclo[3.3.1]non-1-ene. Bredt Compounds and the Bredt Rule Dr. Gert Köbrich Angew. Chem. Int. Ed. 1973,…
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…molecules (you draw them in, and use the ‘name molecule feature’ and it tells you the IUPAC nomenclature. —- I use Yahoo Answers and chemicalforums.com (the organic section) when I…
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…of ethers Opening of epoxides Reactions of thiols In my experience, there’s nothing that helps doing this like making a “map” of reactions. So let’s put each of these reactions…
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…a bespectacled, soft-spoken organic chemistry instructor wrote this reaction on the board. “This is called the Cope rearrangement”, said the instructor. “It’s a rearrangement of 1,5- dienes.” I’m slouching in…
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I love getting letters from people about their experiences with organic chemistry. I love it even more when they share some of the techniques and strategies they used to do…
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…Problems Intramolecular reactions [i.e. reactions where two functional groups in a molecule react with each other] cause a surprising amount of consternation on the part of students. These reactions come…
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…modern computational techniques, we can calculate charge densities extremely well. From these calculations, it’s easy to see where charge is distributed throughout the molecule. For example, ClO- below; oxygen is…
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…mention a second key factor that can complicate the analysis of electron densities: the presence of double bonds (π bonds). In this post we will see how combining an understanding…
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