All About Enamines
…example, an enamine treated with CH3I will form a new C-C bond. This is an example of enamine alkylation. A new carbon-carbon bond is formed. For convenience, water is often…
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The Marriage May Be Bad, But the Divorce Still Costs Money
Common misconception: energy is released through the breaking of bonds. Not correct. Energy is released through the FORMATION of chemical bonds. Formation of a new bond between two atoms results…
Read moreThe Robinson Annulation
…they know a reaction cold – but when suddenly confronted with an example of a nucleophile and an electrophile together on the same molecule, they freeze. This is despite the…
Read moreCarbonyl Chemistry: Learn Six Mechanisms For the Price Of One
…it comes to exam time. Just remember this: Protonation / 1,2-Addition / Proton transfer / 1,2-Elimination / Deprotonation. PAPED. I’ve been trying to come up with a good mnemonic for…
Read moreOrganic Chemistry IUPAC Nomenclature Demystified With A Simple Puzzle Piece Approach
…of chain Suffix = highest priority functional group And so your simple approach is as follows: When you come across a complex molecule with multiple components to name, identify each…
Read moreExam Tip: Don’t just bring your model kit – USE it!
…brought to the exam. Look at this example. Using a line drawing or a Fischer projection to make a model is relatively straightfoward. Therefore, with the assistance of a model,…
Read moreSynthesis (2) – Reactions of Alkanes
…synthetic standpoint!]. You might recall there are two important free-radical halogenation reactions of alkanes: free radical chlorination, and free-radical bromination. Table of Contents Free-Radical Chlorination of Alkanes Free-Radical Bromination of…
Read moreHow Concepts Build Up In Org 1 (“The Pyramid”)
…stereochemistry – “geometric isomers” (e.g. cis/trans isomers in cycloalkanes and alkenes) being the prime example. Level 4– Now comes the chapter on stereochemistry, which is probably the key theme of…
Read moreSummary Sheet: Reactions of Alkenes
…Do you have an exam on alkene and alkynes coming up? We went through hundreds of exams and hand-picked the most “classic” types of questions you’re likely to see on…
Read moreSynthesis (4) – Alkene Reaction Map, Including Alkyl Halide Reactions
…how can the sequence alkane –> alkyl halide –> alkene –> alkane be accomplished? Feel free to post your answers in the comments below! 4. Combined Reaction Map: Reactions of…
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