…“free radical substitution”. In this post we introduce the concepts of homolytic bond breakage, single-barbed curved arrows, free radicals, and free-radical substitution through the example of chlorination of alkanes with…
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…well for her peers. Essentially, this is a complaint about what was tested on the exam. Had her instructor tested people on their knowledge of mechanisms, she would have aced…
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…the order of bond strengths goes primary C-H > secondary C-H > tertiary C-H. Notes Related Articles Free Radical Reactions 3 Factors That Stabilize Free Radicals Selectivity in Free Radical…
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…hired a team of chemists to join his new company, Syntex. As Syntex grew, competitors emerged, and these efforts drove the cost of progesterone down from $80/gram to about $2/gram…
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…out for these types of examples as they are common exam questions. Mechanism: In the SN2 reaction the nucleophile (RO-) attacks the carbon with the good leaving group, forming a…
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…and complaints of other people talking about how hard the course was – actually got her psyched out and affected her success. She needed to re-take the class. The second…
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…relatively “free” and react faster with electrophiles, relative to their rates in polar protic solvents. [See article – Polar Protic? Polar Aprotic? All About Solvents] Here are some common solvents…
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…either as the reactant (example 1) or above the arrow (example 2). It is also common to see the alkyne as starting material with a two-step deprotonation/SN2 process (example 4)….
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…more] via GIPHY via GIPHY via GIPHY via GIPHY [See channel for more] A link to Master Organic Chemistry [https://www.masterorganicchemistry.com] on a public-facing page on a university website would be…
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…SUNY at Stony Brook’s Random Exam Generator (awesome) A lot of good old o-chem exams can be found at AceOrganicChem University of Maryland Tough, but fun old Princeton exams from…
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