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Organic Chemistry For the MCAT
…demonstrate the ability to think independently and to reason critically. As a result the MCAT examination does more than simply test an examinee’s knowledge of a particular subject. One should…
Read moreInitiation, Propagation, Termination
Initiation, Propagation, and Termination In Free Radical Reactions In the previous post on free radical substitution reactions we talked about why heat or light is required in free-radical reactions (See…
Read moreThe Robinson Annulation
Description: The Robinson annulation is a method for forming six membered rings. It is a sequential combination of the Michael reaction and the Aldol condensation. The rest of this page…
Read moreSelectivity in Free Radical Reactions: Bromination vs. Chlorination
…85 (19), 2976-2983 DOI: 1021/ja00902a022 Significant solvent effects are observed in the free-radical photochlorination of benzylic compounds. Complexation by solvent can significantly attenuate the reactivity of the chlorine radical, making…
Read moreSuccess Stories: How Stu Aced Organic Chemistry
…every exam. This included conceptual, technical, and cognitive mistakes. For example, I did horrible on my first exam, considering the amount of time I invested in it. I wasn’t lacking…
Read moreHalogenation At Tiffany’s
…Allylic Bromination Initiation, Propagation, Termination Selectivity in Free Radical Reactions: Bromination vs. Chlorination In Summary: Free Radicals 3 Factors That Stabilize Free Radicals Free Radicals Practice Quizzes (MOC Membership required)…
Read moreThe Mannich Reaction
…iminium). The rest of this page is available to MOC Members only. To get access to this page, plus over 1500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2…
Read moreSelectivity In Free Radical Reactions
…Radical Stability In Summary: Free Radicals 3 Factors That Stabilize Free Radicals Free Radical Bromination of Alkanes (MOC Membership) Initiation, Propagation, Termination (Advanced) References and Further Reading The unusual and…
Read moreMonochlorination Products Of Propane, Pentane, And Other Alkanes
…net formation of new free radicals) and termination (where radicals combine, resulting in a net reduction of the number of free radicals). There’s one simple extension of this reaction I’d…
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