Thiols And Thioethers
…due to their decreased basicity. Since it comes up so much in exams, the intramolecular version is important to note. You’ll see that we’re still forming C–S here and breaking…
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Meet the (Most Important) Functional Groups
All About Functional Groups Functional groups are specific groupings of atoms within molecules that have their own characteristic properties, regardless of the other atoms present in a molecule. Common examples…
Read moreProtecting Groups For Alcohols
…completely uncool to the untrained eye that only a hipster could appreciate it. Then you come to one of those annoying wall outlets. You could paint over it of course….
Read moreElimination of Alcohols To Alkenes With POCl3
…alcohols! Note that this reagent isn’t covered in all courses, but I’ll include it here for completeness’ sake. We’ve talked about 2 ways to convert alcohols to alkenes so far:…
Read morePartial reduction of alkynes to trans alkenes using sodium and ammonia
Description: Alkynes treated with sodium in ammonia are reduced to trans alkenes. Alternatively, potassium in ammonia can also be used. The rest of this page is available to MOC Members…
Read moreMy Recent Absence, Explained With 9 Molecules
…of propafol it is remarkable how close it is to the structure of the common food additive BHT. I wonder if BHT has ever been tested for anaesthetic properties? …
Read moreOptical Purity and Enantiomeric Excess
…surprising for two reasons. First, racemic acid was thought at the time to be a single compound. It turned out to be a 50:50 mixture of two compounds! Second, racemic…
Read moreOxymercuration: Alcohols from alkenes using Hg(OAc)2 and Water
…Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life Example: Org. Synth. 1973, 53, 94 DOI Link: 10.15227/orgsyn.053.0094 Click to Flip…
Read moreMaking Alkyl Halides From Alcohols
…Alkyl Halides From Alcohols Rearrangement Example #1: Hydride Shift Rearrangement Example #2: Alkyl Shift Rearrangement Example #3: A Special Case of Alkyl Shift – Ring Expansion and Contraction What Doesn’t…
Read moreOxymercuration of Alkenes to form Ethers using Hg(OAc)2
…quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life Example: Org. Synth. 1940, 20, 81 DOI…
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