Bond Dissociation Energies = Homolytic Cleavage
…the order of bond strengths goes primary C-H > secondary C-H > tertiary C-H. Notes Related Articles Free Radical Reactions 3 Factors That Stabilize Free Radicals Selectivity in Free Radical…
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SN2 reaction of carboxylate ions with alkyl halides to give esters
…get access to this page, plus over 1500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life…
Read moreSN2 reaction of amines with alkyl chlorides to give ammonium salts
…this page is available to MOC Members only. To get access to this page, plus over 1500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards,…
Read moreThe Organic Chemistry Behind “The Pill”
…hired a team of chemists to join his new company, Syntex. As Syntex grew, competitors emerged, and these efforts drove the cost of progesterone down from $80/gram to about $2/gram…
Read moreSN2 reaction of alkoxide ions with alkyl halides to give ethers (Williamson synthesis)
…out for these types of examples as they are common exam questions. Mechanism: In the SN2 reaction the nucleophile (RO-) attacks the carbon with the good leaving group, forming a…
Read moreDeciding SN1/SN2/E1/E2 (2) – The Nucleophile/Base
…relatively “free” and react faster with electrophiles, relative to their rates in polar protic solvents. [See article – Polar Protic? Polar Aprotic? All About Solvents] Here are some common solvents…
Read moreHow Tyrell Got The Highest Grade In Her Organic Chemistry Course
…nostalgic. My review involved reading my in-class notes, the corresponding book sections, and then combining them to synthesize new “master” notes. Then, I would complete the in-chapter exercises as well…
Read moreResource Guide
…summaries of different reactions This page at Claremont College has quizzes on different reactions This page has practice multiple-choice concept tests These starburst problems can be good for learning reactions…
Read moreResources for Instructors
…on reactions commonly encountered in introductory organic chemistry, generally adhering to content on the ACS organic chemistry exams. Organic Chemistry Reaction Guide Each Reaction Guide page contains a canonical example,…
Read morePartial Reduction of Alkynes With Lindlar’s Catalyst
…(Ni2B). The stereochenistry of this reaction is very commonly tested in exams, expecially in combination with reactions of alkenes that are also stereospecific (e.g. halogenation, dihydroxylation). Note that it’s also…
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