Epoxide Ring Opening With Base
…(RO- ) in alcohol solvent, they lead to essentially the same reaction. Here’s an example with NaOCH3. Note that the proton must come from CH3OH here. 2. The Role Of…
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Opening of Epoxides With Acid
…example: So in essence, the addition of nucleophiles to protonated epoxides is just another example of the “3 membered ring pathway” of alkenes! [Need a review on why the nucleophile…
Read moreOxidation of thiols to disulfides
…Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life Example: Org. Synth. 1948, 28, 16 DOI Link: 10.15227/orgsyn.028.0016 Click to Flip…
Read moreOrganic Chemistry Study Advice
…Tips: Reaction Maps Organic Chemistry Study Tips: Exam Preparation “America’s Top TA” Shares His Secrets for Studying O-Chem Common Mistakes: Pentavalent Carbon Common Mistakes: Resonance Arrows Common Blind Spot: Intramolecular…
Read moreAlcohols To Ethers via Acid Catalysis
…(1-3), 327-335 DOI: 10.1016/S0920-5861(98)00440-4 This paper shows that the mechanism for formation of symmetrical ethers from secondary alcohols (e.g. isopropanol) is more complex, as bimolecular dehydration can compete with other…
Read moreEthers From Alkenes, Tertiary Alkyl Halides and Alkoxymercuration
…327-335 DOI: 1016/S0920-5861(98)00440-4 This paper shows that the mechanism for formation of symmetrical ethers from secondary alcohols (e.g. isopropanol) is more complex, as bimolecular dehydration can compete with other pathways…
Read moreThe Williamson Ether Synthesis
…gives you two alkyl halide + alkoxide combinations to choose from. Let’s start with a fairly easy example. See if you can come up with reasonable starting materials for the…
Read moreOxidation of aldehydes to carboxylic acids with Ag2O
Description: When Ag2O is added to aldehydes, carboxylic acids are formed. This results in the formation of silver metal (“silver mirror”) a reaction known as the Tollens test. The rest…
Read moreFrom a “Drop” To B+ in Org 2 – How A Hard Working Student Turned It Around
…mark). I decided to do as much as I could to guarantee I’d pass the course, and it turned out I not only passed, but did so with flying colors…
Read moreOxidation of aromatic alkanes with KMnO4 to give carboxylic acids
…as in example 1. And in example 3, two benzoic acids are formed. Finally, when no hydrogens are present on the benzylic carbon, no reaction occurs (example 4). Mechanism: For…
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