Alcohol Oxidation: “Strong” and “Weak” Oxidants
…a ketone, which we showed in example 2 and also with a “stronger” oxidant in example 3. And in example 4 we showed that oxidation “up” from a tertiary alcohol…
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Pinacol Rearrangement
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Read moreMy Recent Absence, Explained With 9 Molecules
…penicillin by synthesizing proteins that break open the beta-lactam ring without harming the organism [beta lactamases]. Taking the arms race one step further, zosyn combines the penicillin antibiotic piperacillin with…
Read moreOptical Purity and Enantiomeric Excess
…The Mixture Now comes the part which sometimes trips people up. What’s the molar composition of the mixture? Your first answer might be 50:50. 50% d- and 50% l- ….
Read moreOzonolysis of alkenes to ketones and aldehydes (reductive workup)
Description: Ozone will cleave carbon-carbon double bonds to give carbonyl compounds such as aldehydes or ketones, after treatment with a reducing agent such as zinc or dimethyl sulfide (“reductive workup”)…
Read moreMaking Alkyl Halides From Alcohols
…Alkyl Halides From Alcohols Rearrangement Example #1: Hydride Shift Rearrangement Example #2: Alkyl Shift Rearrangement Example #3: A Special Case of Alkyl Shift – Ring Expansion and Contraction What Doesn’t…
Read morePBr3 and SOCl2
…Using a milder, more targeted reagent would help us avoid undesired side reactions in more complex situations. A harder point to address is this: why not just, for example, always…
Read moreOxymercuration: Alcohols from alkenes using Hg(OAc)2 and Water
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Read moreEpoxides – The Outlier Of The Ether Family
…molecules – see how the second and third examples open to give linear products. By the way, that first example is the answer to the quiz at the bottom of…
Read moreOxymercuration of Alkynes
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