Reactions of Grignard Reagents
…to give carboxylic acids (after acid workup). Grignard reagents will not perform SN2 reactions with alkyl halides. They are also not compatible with carboxylic acids or alcohols. Table of Contents…
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Natural Product Isolation (2) – Purification Techniques, An Overview
…sometimes (rarely) we get lucky and obtain an extract that is predominantly one compound, a more representative situation is that a mixture of compounds is obtained. For instance, this gas…
Read moreOur New Book, “Practice Organic Mechanisms”, Is Out
…different version: Practice Organic Mechanisms addresses this by providing multiple examples of the same reaction, with space provided for students to draw electron-pushing arrows. For example, in the section on…
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…chemistry topics. With over 500 free articles that reach over 5 million visitors / year, MOC was recently ranked the world’s #10 most visited chemistry website. (SimilarWeb.com, December 2018) …
Read moreKiliani-Fischer Synthesis
Description: The Kiliani-Fischer synthesis is a way of extending sugars by one carbon. It leads to a mixture of stereoisomers. The rest of this page is available to MOC Members…
Read moreFormation of Grignard and Organolithium Reagents
Formation or Grignard Reagents and Organolithium Reagents From Alkyl and Alkenyl Halides In the last post we introduced the concept of organometallic compounds – molecules where carbon is bound to…
Read moreNew IUPAC Rules Make Molecular Names More Pronounceable, Friendlier
…for the naming of new compounds. “As of today, all 50 million known chemical compounds must be re-named to standards that allow for a typical American third grader to be…
Read moreWhat’s An Organometallic?
…Molecules which contain a carbon-metal bond are known as organometallic compounds Examples of organometallic compounds include organolithium compounds, organomagnesium compounds (Grignard reagents) and organocuprates (Gilman reagents) Table of Contents A…
Read moreOn Cats, Part 1: Conformations and Configurations
…the same cat, but the shapes have different comfort levels due to the impact of gravity (among other things). The orientation on the left is more comfortable, hence lower energy,…
Read moreHydrolysis of nitriles with aqueous acid to give carboxylic acids
…to this page, plus over 2500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-World Examples: Org….
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