Protection of alcohols as silyl ethers
…alcohols. The rest of this page is available to MOC Members only. To get access to this page, plus over 2500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2…
Read moreMaster Organic Chemistry Reaction Guide
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Rearrangement Reactions (1) – Hydride Shifts
…From Alcohols Quiz Yourself! Become a MOC member to see the clickable quiz with answers on the back. Become a MOC member to see the clickable quiz with answers…
Read moreAlcohols To Ethers via Acid Catalysis
…shows that the mechanism for formation of symmetrical ethers from secondary alcohols (e.g. isopropanol) is more complex, as bimolecular dehydration can compete with other pathways (e.g. SN1 or elimination-addition). Diisopropyl…
Read moreEthers From Alkenes, Tertiary Alkyl Halides and Alkoxymercuration
…327-335 DOI: 1016/S0920-5861(98)00440-4 This paper shows that the mechanism for formation of symmetrical ethers from secondary alcohols (e.g. isopropanol) is more complex, as bimolecular dehydration can compete with other pathways…
Read moreThe Williamson Ether Synthesis
…gives you two alkyl halide + alkoxide combinations to choose from. Let’s start with a fairly easy example. See if you can come up with reasonable starting materials for the…
Read moreAlcohols – Acidity and Basicity
…of the weak acid H2O (pKa 14) is the strongly basic hydroxide ion (HO-). 2. Examples of Acid-Base Reactions Of Alcohols Here’s an example of a favorable acid-base reaction of…
Read morePinacol Rearrangement
…this page is available to MOC Members only. To get access to this page, plus over 2500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards,…
Read moreAlcohols – Nomenclature and Properties
…detail, and I will happily refer you to those for now. Here’s an example by Leah Fisch, for example. 2. Physical Properties of Alcohols: Hydrogen Bonding The key to understanding…
Read moreHow Serge Aced Organic Chemistry
…will have a different method/structure to their exams. If you can get your hands on an old exam or if your instructor puts up practice exams (usually just old exams)…
Read moreOzonolysis of alkenes to ketones and aldehydes (reductive workup)
Description: Ozone will cleave carbon-carbon double bonds to give carbonyl compounds such as aldehydes or ketones, after treatment with a reducing agent such as zinc or dimethyl sulfide (“reductive workup”)…
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