Now Available – The Spectroscopy Pack (PDF)
One of the most common complaints I hear from readers of Master Organic Chemistry is that there isn’t a lot of coverage of spectroscopy. And I’ve been sorry to say,…
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Hydrogenation of Alkenes to give Alkanes
…Real-Life Examples: Org. Synth. 1928, 8, 36 DOI Link: 10.15227/orgsyn.008.0036 Click to Flip Org. Synth. 1937, 17, 45 DOI Link: 10.15227/orgsyn.017.0045 Click to Flip Org. Synth. 1957, 37, 77 DOI…
Read moreIR Spectroscopy: 4 Practice Problems
…We were able to use it to “rule out” a few answers which you might classify as “trick questions”. Next, we examined the hydroxyl region around 3200-3400 cm for broad,…
Read moreDiastereotopic Protons in 1H NMR Spectroscopy: Examples
…the protons’ diastereotopic relationships. Replacing Ha with D leads to the (R,R) compound, while replacing Hb with D leads to the (R,S) compound. The two new compounds are diastereomers, confirming…
Read moreHomotopic, Enantiotopic, Diastereotopic
…When Does It Matter? Notes 1. When Is “Homotopic, Enantiotopic, Diastereotopic” Important? Certain reactions directly replace hydrogens with other atoms. For example, free radical chlorination replaces C-H bonds with C-Cl…
Read moreHydroboration of alkynes using R2BH or BH3 to give aldehydes
Description: When alkynes are treated with BH3 and subsequently treated with H2O2, they are converted into aldehydes. The rest of this page is available to MOC Members only. To get…
Read moreHow To Succeed In Organic Chemistry
Successful Organic Chemistry Students Share Their Secrets Thanks for subscribing! Click here to download the e-book. Once it’s loaded in your browser, “Save As” a file to your desktop….
Read moreHydroboration of Alkenes
…HOOH or any other comparably acidic species as the acid. Quiz Yourself! Click to Flip Click to Flip Click to Flip Exam-Type Examples Click to Flip Click to Flip Click…
Read moreHow To Succeed In Organic Chemistry
Thanks for subscribing! Click here to download the e-book. Once it’s loaded in your browser, “Save As” a file to your desktop….
Read moreOptical Rotation, Optical Activity, and Specific Rotation
…Comparing Optical Rotation Now comes the final piece of the puzzle: standardization. It would be useful to have a common standard for optical rotation that allowed us to compare samples…
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