Polymerization of dienes with acid
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Read moreMaster Organic Chemistry Reaction Guide
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Pinacol Rearrangement
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Read moreElimination of Alcohols To Alkenes With POCl3
…alcohols! Note that this reagent isn’t covered in all courses, but I’ll include it here for completeness’ sake. We’ve talked about 2 ways to convert alcohols to alkenes so far:…
Read moreMy Recent Absence, Explained With 9 Molecules
…the standard battery of tests, doctors told me that my platelet count was 34. Normal humans have platelet counts of 150-300. Below 20 they immediately start blood infusions. The diagnosis…
Read moreElimination Reactions of Alcohols
…and formed a new C-C π bond at that spot. It’s reasonable to propose that instead of attacking the carbocation to form a new substitution product, a base removed a…
Read morePartial reduction of alkynes with Lindlar’s catalyst to give cis alkenes
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Read morePartial reduction of alkynes to trans alkenes using sodium and ammonia
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Read moreOptical Purity and Enantiomeric Excess
…surprising for two reasons. First, racemic acid was thought at the time to be a single compound. It turned out to be a 50:50 mixture of two compounds! Second, racemic…
Read morePBr3 and SOCl2
…Using a milder, more targeted reagent would help us avoid undesired side reactions in more complex situations. A harder point to address is this: why not just, for example, always…
Read moreOzonolysis of alkenes to ketones and aldehydes (reductive workup)
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