Oxidation of primary alcohols to carboxylic acids
Description: Primary alcohols treated with chromic acid will be converted to carboxylic acids. The rest of this page is available to MOC Members only. To get access to this page,…
Read moreMaster Organic Chemistry Reaction Guide
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Alcohols To Ethers via Acid Catalysis
…(1-3), 327-335 DOI: 10.1016/S0920-5861(98)00440-4 This paper shows that the mechanism for formation of symmetrical ethers from secondary alcohols (e.g. isopropanol) is more complex, as bimolecular dehydration can compete with other…
Read moreOxidation of secondary alcohols to ketones using PCC
Description: Treatment of secondary alcohols with pyridinium chlorochromate (PCC) leads to ketones. The rest of this page is available to MOC Members only. To get access to this page, plus…
Read moreEthers From Alkenes, Tertiary Alkyl Halides and Alkoxymercuration
…327-335 DOI: 1016/S0920-5861(98)00440-4 This paper shows that the mechanism for formation of symmetrical ethers from secondary alcohols (e.g. isopropanol) is more complex, as bimolecular dehydration can compete with other pathways…
Read moreThe Williamson Ether Synthesis
…gives you two alkyl halide + alkoxide combinations to choose from. Let’s start with a fairly easy example. See if you can come up with reasonable starting materials for the…
Read moreOxidation of aldehydes to carboxylic acids with Ag2O
…of this page is available to MOC Members only. To get access to this page, plus over 1500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and…
Read moreOxidation of aromatic alkanes with KMnO4 to give carboxylic acids
…as in example 1. And in example 3, two benzoic acids are formed. Finally, when no hydrogens are present on the benzylic carbon, no reaction occurs (example 4). Mechanism: For…
Read moreAlcohols – Acidity and Basicity
…stabilizes the conjugate base will increase acidity. Here’s another example. Compare ethanol (pKa 16) to 2,2,2-trifluoroethanol (pKa about 12). Why do you think trifluoroethanol is more acidic? Compare their conjugate…
Read moreOrganic Chemistry Practice Questions
…answer all the questions in your exams, we worked through hundreds of organic chemistry exams and put together 2500+ practice questions, inspired by real-world exams. These cover common and trick…
Read moreOn Cats, Part 2: Cat Line Diagrams
…cat science, I’ve lost any compunctions I might have had earlier. Want gratuitous cat pictures? You bet. Introducing the Cat Line Diagram But this blog is really about breaking new…
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