Formation of organolithium reagents from alkyl halides
Description: Addition of lithium metal (2 equiv) to an alkyl or alkenyl halide results in formation of the organolithium reagent. The rest of this page is available to MOC Members…
Read moreMaster Organic Chemistry Reaction Guide
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Why Are Endo vs Exo Products Favored in the Diels-Alder Reaction?
…just confine ourselves to examining the “primary” molecular orbitals – i.e. the molecular orbitals involved in bond formation. The key difference comes when we extend our view and look the…
Read moreAntiaromatic Compounds and Antiaromaticity
…8 Pi-Electron Example of an Antiaromatic Compound: Pentalene What Makes A Molecule Anti-Aromatic? Cyclooctatetraene “Escapes” Anti-Aromaticity Through Twisting Out Of Flatness Conclusion: Antiaromatic Compounds Notes Advanced: References and Further Reading…
Read moreHOMO and LUMO In the Diels Alder Reaction
…is why the Diels-Alder actually works. After all, we’ve seen plenty of examples of things that don’t work; two alkenes, for example, don’t combine to form four membered rings upon…
Read moreFormation of Grignard Reagents from Alkyl Halides
…this page, plus over 2500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life Examples DOI Link:…
Read moreFormation of Grignard Reagents from Alkenyl Halides
…for only 30 cents/ day! Real-Life Examples: Org. Synth. 1945, 25, 11 DOI Link: 10.15227/orgsyn.025.0011 Click to Flip Org. Synth. 1948, 28, 28 DOI Link: 10.15227/orgsyn.028.0028 Click to Flip Org….
Read moreFormation of Gilman reagents (organocuprates) from alkyl halides
Description: Alkyl halides will react with lithium metal (Li) to make organolithium reagents. When two equivalents of organolithium are combined with a copper halide, this will form organocuprates (Gilman reagents)…
Read moreReactions of Diazonium Salts: Sandmeyer and Related Reactions
…structure of which is two benzene molecules joined by a nitrogen-nitrogen double bond. See this article on azo dyes, for instance. Yellow, red, and orange are common colors of azo…
Read moreIntroduction to Peptide Synthesis
…an idea of the process. At about 0:34 you can see how small the beads are. https://www.youtube.com/watch?v=jVXUfC2pLh4 The starting point for the Merrifield process is crosslinked polystyrene. which behaves like…
Read moreFormation of Cyanohydrins from ketones and aldehydes
…flashcards, sign up here for only 30 cents/ day! Real-Life Examples: Org. Synth. 1942, 22, 13 DOI Link: 10.15227/orgsyn.022.0013 Click to Flip Org. Synth. 1935, 15, 3 DOI : 10.15227/orgsyn.015.0001…
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