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Read more…Again, examining the pi molecular orbitals will give us some useful clues. Notably, in cyclobutadiene, the highest-occupied molecular orbitals are unpaired electrons of equal energy. Table of Contents Building Up…
Read more…1. The Commonly Used “Cyclopentadiene” Can’t Be Bought From Chemical Suppliers. Why? Let’s talk about cyclopentadiene, a commonly used diene for Diels-Alder reactions that, by the way, comes up all…
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Read more…Example #1 Determining R and S Configuration On Newman Projections: Example #2 Determining R and S On A Newman With An Eclipsed Conformation: Example #3. Conclusion: Determining R and S…
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Read more…it does, it’s usually when you’re sitting in an exam hall. What makes the retro-Diels Alder reaction exam-question catnip for instructors is that it asks you to apply concepts you…
Read more…really ambitious, let’s do: methyl (1R,2R,3S,5S)-3- (benzoyloxy)-8-methyl-8-azabicyclo[3.2.1] octane-2-carboxylate and methyl (1S,2S,3R,5R)-3- (benzoyloxy)-8-methyl-8-azabicyclo[3.2.1] octane-2-carboxylate. Same IUPAC descriptor, opposite (R,S)-descriptors: enantiomers. Step 3: Double Check That They’re Not Meso What about (S,R)-2,3-dibromobutane…
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