Free Radical Chlorination of Alkanes
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Read moreMaster Organic Chemistry Reaction Guide
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Free Radical Bromination of Alkanes
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Read moreDiels-Alder Reaction: Kinetic and Thermodynamic Control
…1. The Commonly Used “Cyclopentadiene” Can’t Be Bought From Chemical Suppliers. Why? Let’s talk about cyclopentadiene, a commonly used diene for Diels-Alder reactions that, by the way, comes up all…
Read moreFree Radical Addition of HBr To Alkenes
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Read moreAssigning R/S To Newman Projections (And Converting Newman To Line Diagrams)
…Example #1 Determining R and S Configuration On Newman Projections: Example #2 Determining R and S On A Newman With An Eclipsed Conformation: Example #3. Conclusion: Determining R and S…
Read moreThe Retro Diels-Alder Reaction
…it does, it’s usually when you’re sitting in an exam hall. What makes the retro-Diels Alder reaction exam-question catnip for instructors is that it asks you to apply concepts you…
Read moreEnantiomers vs Diastereomers vs The Same? Two Methods For Solving Problems
…really ambitious, let’s do: methyl (1R,2R,3S,5S)-3- (benzoyloxy)-8-methyl-8-azabicyclo[3.2.1] octane-2-carboxylate and methyl (1S,2S,3R,5R)-3- (benzoyloxy)-8-methyl-8-azabicyclo[3.2.1] octane-2-carboxylate. Same IUPAC descriptor, opposite (R,S)-descriptors: enantiomers. Step 3: Double Check That They’re Not Meso What about (S,R)-2,3-dibromobutane…
Read moreWhy Are Endo vs Exo Products Favored in the Diels-Alder Reaction?
…over exo products in the Diels-Alder reaction. [We also introduced a quick-and-dirty rule for telling the difference between endo- and exo- products in the Diels-Alder.] So why are endo products…
Read moreFormation of organolithium reagents from alkyl halides
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Read moreFormation of imines from primary amines and ketones
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