s-cis and s-trans
…that there is free rotation about sigma bonds, so we say, “s-cis” and “s-trans” to distinguish it from “cis” and “trans” configurations which are locked. As we’ll soon see, in…
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More On 1,2 and 1,4 Additions To Dienes
…Addition Pattern – Free Radical Addition Note 1. This example was inspired by an exam question I once saw from an instructor/university I choose not to mention, which gave “1,4”…
Read moreDihydroxylation of alkenes with cold, dilute KMnO4 to give vicinal diols
Description: Treatment of alkenes with cold, dilute basic KMnO4 leads to 1,2-diols (vicinal diols). The rest of this page is available to MOC Members only. To get access to this…
Read moreDiels Alder Reaction of dienes and dienophiles
…for only 30 cents/ day! Real-Life Examples: Org. Synth. 1952, 32, 41 DOI Link: 10.15227/orgsyn.032.0041 Click to Flip Org. Synth. 1950, 30, 93 DOI Link: 10.15227/orgsyn.030.0093 Click to Flip Org….
Read moreThe Big Damn Post Of Carbohydrate-Related Chemistry Definitions
…pyranose versus furanose, and all the other most commonly encountered carbohydrate-related terms in a typical second-semester organic chemistry course. [This reference document from IUPAC was extremely helpful in the preparation…
Read moreDiels Alder Practice Problems
These practice questions will test you on recognizing conjugated dienes, comparing the reactivity of dienes in the Diels-Alder reaction, providing the major products of Diels-Alder reactions, understanding how to apply…
Read moreSynthesis of Benzene Derivatives (2) – Polarity Reversal
…The ketone is just one of other possible examples. As the pathways below try to show, alkyl halides are a gateway not only to the many compounds possible from nucleophilic…
Read moreAromatic Synthesis (1) – “Order Of Operations”
…of Contents Synthesis of Aromatic Compounds: “Order of Operations” Matters Example #1: Synthesis of m-Bromonitrobenzene From Benzene Example #2:Synthesis of p-Ethylacetophenone From Benzene Summary: To Obtain The Para- Product, Install…
Read moreSome Reactions of Azides
…DOI: 10.1002/0471264180.or003.09 An old but comprehensive review of the Curtius reaction, which includes the history of the discovery of this rearrangement, substrate scope, limitations, comparison to other similar reactions, and…
Read moreCurtius Rearrangement of Acyl Azides to Isocyanates
…Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life Example: Org. Synth. 1944, 24, 94 DOI Link: 10.15227/orgsyn.024.0094 Click to Flip…
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