How To Determine Hybridization: A Shortcut
…you haven’t mastered line diagrams yet (and “hidden” hydrogens) maybe get some more practice and come back to this later.] Click to Flip Here are some more examples. Click to…
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Formation of Amides Using DCC
Description: Treatment of carboxylic acids with amines in the presence of the dehydrating agent N,N’-dicyclohexylcarbodiimide (DCC) leads to the formation of amides. This is particularly useful for peptide synthesis. The…
Read moreSynthesis (7): Reaction Map of Benzene and Related Aromatic Compounds
Reactions of Benzene and Aromatic Compounds: A Reaction Map (PDF) Let’s map out all of the reactions we’ve learned in this section on aromatic rings + substituents. The list comes…
Read moreReactions of Sugars: Glycosylation and Protection
…an excess of alcohol in the presence of acid (such as H2SO4). Simple sugars (e.g., D-Glucose) have a hemiacetal functional group due to the fact that 5- and 6- membered…
Read moreFormation of amides from acid chlorides and amines
…this page, plus over 1500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life Examples: Org. Synth….
Read moreThe Ruff Degradation and Kiliani-Fischer Synthesis
…carbohydrate chain by a single carbon. The Kiliani-Fischer Synthesis involves addition of cyanide ion to an open-chain aldehyde (in the case of aldoses) which is then partially reduced and then…
Read moreSodium Borohydride (NaBH4) Reduction of Aldehydes and Ketones
…Compounds with NaBH4 Summary Notes Quiz Yourself! (Advanced) References and Further Reading 1. Sodium Borohydride (NaBH4 ) Sodium borohydride (NaBH4) can be made through the addition of sodium hydride (NaH)…
Read moreFormation of alkynes through double elimination of vicinal dibromides
…this page, plus over 1500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day! Real-Life Examples: Org. Synth….
Read moreFormation of Acetals from Aldehydes and Ketones
…To get access to this page, plus over 1500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day!…
Read moreHybrid Orbitals and Hybridization
…an atom or even leave the atom altogether. What is surprising is when we open up the fridge and find that our cute little sphere- and dumbbell-shaped Tupperware containers have…
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