The Hofmann Elimination
…3. The “Hofmann Degradation” Back in 1851, not many techniques for analyzing complex molecules were available. One method for determining the structure of an unknown compound was to break it…
Read more…3. The “Hofmann Degradation” Back in 1851, not many techniques for analyzing complex molecules were available. One method for determining the structure of an unknown compound was to break it…
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Read more…that there is free rotation about sigma bonds, so we say, “s-cis” and “s-trans” to distinguish it from “cis” and “trans” configurations which are locked. As we’ll soon see, in…
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Read more…Azide Salts: Acyl Azides Rearrangement of Acyl Azides: The Curtius Rearrangement More Examples of Azide Nucleophiles: Epoxide Opening And Conjugate Addition Notes (Advanced) References and Further Reading 1. The Azide…
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Read more…bottom. But first, for completeness, let’s cover two other reactions of dienes that can lead to 1,2- and 1,4- addition products. Addition of HBr to dienes under free-radical conditions Addition…
Read more…Open-Chain Aldehyde So What Isn’t A Reducing Sugar? Saccharides Lacking A Hemiacetal Are NOT Reducing Sugars Complex Polysaccharides With A single Hemiacetal Unit (e.g. Starch) Are Not Reducing Sugars Test…
Read more…“Order of Operations” Is Important What Do We Do When Directing Groups Don’t Direct The “Right Way” ? Ortho-, Para- Directors From Meta- Directors: 3 Examples Meta- Directors From Ortho-,…
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