Introduction To Aromaticity
…compounds in equilibrium will result in about a 99:1 distribution towards the more stable component (remember cyclohexane chair A-values?) Note 2. There’s a fourth diagnostic property of aromaticity – ring…
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Isoelectric Points of Amino Acids (and How To Calculate Them)
…will bear a net positive or net negative charge, respectively. It’s possible to test this by applying a sample of the amino acid to specially treated paper or gel and…
Read moreProtecting Groups for Amines – Carbamates
…carboxylic acid, but a slightly better approach would be to use the methyl ester of alanine to avoid any self-coupling between the free amine of alanine and the free carboxylic…
Read moreFormation of anhydrides from acid halides and carboxylates
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Read moreHow To Determine Hybridization: A Shortcut
…especially. If you haven’t mastered line diagrams yet (and “hidden” hydrogens) maybe get some more practice and come back to this later.] Click to Flip Here are some more examples….
Read moreThe Ruff Degradation and Kiliani-Fischer Synthesis
…carbohydrate chain by a single carbon. The Kiliani-Fischer Synthesis involves addition of cyanide ion to an open-chain aldehyde (in the case of aldoses) which is then partially reduced and then…
Read moreFormation of Amides Using DCC
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Read moreReducing Sugars
…Tollens test (silver mirror precipitate). Tollens’s test, fulminating silver, and silver fulminate Ian D. Jenkins Journal of Chemical Education 1987, 64 (2), 164 DOI: 10.1021/ed064p164 The Tollens test is commonly…
Read moreReactions of Sugars: Glycosylation and Protection
…4. Formation Of Disaccharides (In Theory, If Not In Practice) A particularly important type of glycoside are those formed from the combination of two or more sugars. Maltose, for example,…
Read moreFormation of amides from acid chlorides and amines
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