What To Expect In Organic Chemistry 2
…be very important! Here is a brief introduction to some of the highlights of Org 2. By the end of the course, the answers to the following questions hopefully won’t…
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The Malonic Ester and Acetoacetic Ester Synthesis
…of Contents The Common Pattern In The Malonic Ester Synthesis The Malonic Ester Synthesis Is Comprised Of Five Separate Reactions Step 1: Deprotonation To Give An Enolate Step 2: SN2…
Read moreClaisen Condensation and Dieckmann Condensation
…Note 2. Grossman’s “second-best” rule is handy to know: “The second-best resonance structure often provides the key to understanding the chemical behavior of that compound” (from, “The Art of Writing…
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MOC Member Resources: Go to the Reaction Guide Go to the Practice Quizzes Download the Reaction Flashcards (PDF) Download the Org 1 Summary Sheets (PDF) Download the Org 2 Summary…
Read moreDecarboxylation
…acetoacetic acid synthesis, respectively. We’ll go through some examples, show how not to do the arrow pushing (and how to avoid a common mistake) and then try to explain why…
Read moreA Gallery of Some Interesting Molecules From Nature
…bottom-most six membered ring. This is a common theme in natural product biosynthesis, by the way: complexity by way of oxidation of simpler precursors. Treating morphine with acetic anhydride gives…
Read more350 Examples of Classic Org 1/Org 2 Reactions From “Organic Syntheses”
…Flickr: https://www.flickr.com/photos/182129490@N06/collections The set of 350 .CDX files can be downloaded here for free, along with an XLS that contains the DOIs. Coll Org Syn Chemdraw (.zip) including XLSX spreadsheet…
Read moreIntroduction To UV-Vis Spectroscopy
…reflected, and orange is the complementary color of blue. For example, this molecule, Rhodamine B [Note 3] absorbs at about 560 nm (green) and appears red , the complimentary color…
Read moreNucleophilic Addition To Carbonyls
…Chem. Soc., Trans., 1903,83, 995-1005 DOI: 10.1039/CT9038300995 2.CXXII.—Reactions involving the addition of hydrogen cyanide to carbon compounds. Part II. Cyanohydrins regarded as complex acids Arthur Lapworth J. Chem. Soc., Trans.,…
Read moreAcidic cleavage of ethers (SN2)
…In the case where the ether being cleaved is secondary and has a stereocenter, there will be inversion of configuration. Examples: Notes: The third example could also be written “H3O+”…
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