Conversion of alcohols to alkyl chlorides using SOCl2
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Read moreMaster Organic Chemistry Reaction Guide
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Conversion of alcohols to alkyl bromides using PBr3
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Read moreReactions of Dienes: 1,2 and 1,4 Addition
Kinetic Versus Thermodynamic Control In Addition of HBr to Dienes: 1,2- and 1,4- Addition In today’s post we’ll discuss 1,2- and 1,4- addition to dienes – specifically, the addition of…
Read moreConversion of acid chlorides to esters through addition of an alcohol
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Read moreIntramolecular Friedel-Crafts Reactions
…Enantiospecific synthesis of (+)-(R)-1-phenyl-3-methyl-1,2,4,5-tetrahydrobenz[d]azepine from (+)-(S)-N-methyl-1-phenyl ethanolamine (halostachine) via arene chromium tricarbonyl methodology Steven J. Coote, Stephen G. Davies, David Middlemiss, Alan Naylor Tetrahedron Lett. 1989, 30 (27), 3581-3588 DOI:…
Read moreNucleophilic Aromatic Substitution (NAS)
…placement of electron withdrawing groups ortho- or para- to the leaving group results in faster reactions than does the placement of electron withdrawing groups meta- to the leaving group Fluorine…
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Read moreEAS Reactions (3) – Friedel-Crafts Acylation and Friedel-Crafts Alkylation
…chloride (AlCl3) is often used, but FeCl3 and other Lewis acids will also do the job. Here’s a general example of the Friedel-Crafts acylation: A specific example is the reaction…
Read moreClemmensen Reduction of Ketones/Aldehydes to Alkanes
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Read moreAlkylation of Amines (Sucks!)
…Suck? Trends in the basicity of amines provide a classic example of why chemistry is so interesting; it’s deciphering the delicate trade-offs between various general factors in specific cases that…
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