s-cis and s-trans
…that there is free rotation about sigma bonds, so we say, “s-cis” and “s-trans” to distinguish it from “cis” and “trans” configurations which are locked. As we’ll soon see, in…
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Dihydroxylation of alkenes with cold, dilute KMnO4 to give vicinal diols
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Read moreDiels Alder Practice Problems
These practice questions will test you on recognizing conjugated dienes, comparing the reactivity of dienes in the Diels-Alder reaction, providing the major products of Diels-Alder reactions, understanding how to apply…
Read moreDiels Alder Reaction of dienes and dienophiles
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Read moreThe Big Damn Post Of Carbohydrate-Related Chemistry Definitions
…pyranose versus furanose, and all the other most commonly encountered carbohydrate-related terms in a typical second-semester organic chemistry course. [This reference document from IUPAC was extremely helpful in the preparation…
Read moreMore On 1,2 and 1,4 Additions To Dienes
…Addition Pattern – Free Radical Addition Note 1. This example was inspired by an exam question I once saw from an instructor/university I choose not to mention, which gave “1,4”…
Read moreSome Reactions of Azides
…Azide Salts: Acyl Azides Rearrangement of Acyl Azides: The Curtius Rearrangement More Examples of Azide Nucleophiles: Epoxide Opening And Conjugate Addition Notes (Advanced) References and Further Reading 1. The Azide…
Read moreAromatic Synthesis (1) – “Order Of Operations”
…of Contents Synthesis of Aromatic Compounds: “Order of Operations” Matters Example #1: Synthesis of m-Bromonitrobenzene From Benzene Example #2:Synthesis of p-Ethylacetophenone From Benzene Summary: To Obtain The Para- Product, Install…
Read moreDehydration of amides to give nitriles
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Read moreAldehydes and Ketones: 14 Reactions With The Same Mechanism
…Mechanism Behind This “Two Step” Pattern For Addition Reactions Of Aldehydes And Ketones Here’s the general mechanism. First comes addition of the nucleophile, and second comes protonation of the resulting…
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