Elimination (E2) of alkyl halides to give alkenes
Description: Addition of strong base to an alkyl halide results in elimination to form a new C–C π bond. The rest of this page is available to MOC Members only….
Read moreMaster Organic Chemistry Reaction Guide
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The Wolff-Kishner, Clemmensen, And Other Carbonyl Reductions
…We’ll have more to say about this when we address synthesis in aromatic compounds, but just take a gander at these two examples…. Two more examples of reversing the polarity…
Read moreReactions on the “Benzylic” Carbon: Bromination And Oxidation
…you’re dealing with free radical chlorination. [See: Selectivity in Free-Radical Reactions] We’ve seen that an exception to this “boring” behavior can be found in the free-radical bromination of so-called “allylic”…
Read moreThermodynamic and Kinetic Products
…eat canned Ravioli. However this state of affairs did not last long. Within the next week my $1.14 can opener had opened (poorly!) about three or four cans before flying…
Read moreElimination (E1) Practice Problems And Solutions
…To get access to this page, plus over 2500 quizzes, the Reaction Encyclopedia, Org 1 / Org 2 summary sheets, and flashcards, sign up here for only 30 cents/ day!…
Read moreWhat is Mutarotation?
…OH group on C-1 is on the same side of the ring as the C-5 substituent. Each of these two forms can be synthesized and isolated as pure compounds. The…
Read moreNucleophilic Aromatic Substitution (2) – The Benzyne Mechanism
…Reactions Nucleophilic Aromatic Substitution Via Arynes (MOC Membership) Electrophilic Aromatic Substitution Practice Problems (MOC Membership) Some other examples of substitution Methods for generating benzyne Roberts’ degradation study Some other examples…
Read moreReductive Amination
…One common reducing agent for this purposes is sodium cyanoborohydride (NaBH3CN) which can selectively reduce imines in the presence of aldehydes. Many other reducing agents (NaBH4, NaBH(OAc)3, etc.) can be…
Read moreDihydroxylation of alkenes with cold, dilute KMnO4 to give vicinal diols
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Read moreDiels Alder Practice Problems
These practice questions will test you on recognizing conjugated dienes, comparing the reactivity of dienes in the Diels-Alder reaction, providing the major products of Diels-Alder reactions, understanding how to apply…
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