Cyclopropanation of Alkenes
…kit, you will quickly discover that the little pieces of plastic will not forgive you for trying to bend them into a constrained triangular shape. Given this, it might come…
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Success Stories: How Nathan Aced Organic Chemistry (Without It Taking Over His Life)
…read ahead too far. Before I say why, let me first say that a major part of the studying and learning in this class for me is the composition of…
Read moreNow Available: The Organic Reactions Flashcard App for iPhone
Today, in partnership with Rich Apodaca of Metamolecular, I’m happy to announce the release of a new app for the Apple iOs: Organic Reaction Flashcards for iPhone. It should come…
Read morePalladium on Carbon (Pd/C) for Catalytic Hydrogenation of Alkenes
…has been completely purged of oxygen. Don’t add finely divided metal catalyst to a flask containing hydrogen and oxygen; fires can result this way. Raney nickel comes with H2 already…
Read moreAlkene Addition Pattern #1: The “Carbocation Pathway”
…proceed through the same key steps. They all share the same pattern of regioselectivity and stereoselectivity. Learn one mechanism, learn them all! https://www.masterorganicchemistry.com/wp-content/uploads/2013/02/Carbocation-pathway.mp4 There’s one last wrinkle with this family…
Read moreOxymercuration Demercuration of Alkenes
…Flip 3. The Mechanism of Oxymercuration Goes Through A 3-Membered “Mercurinium Ion” The first step of oxymercuration results in a new organomercury compound with a C-Hg bond. Unlike many compounds…
Read moreOrganic Reaction Flashcards Version 2.0 Is Here!
…version of Organic Reaction Flashcards, and it is significantly better in every way. Here’s the details: 1. More Reactions Our goal was to build a reasonably comprehensive set of flashcards…
Read moreHow John Pulled Up His Organic Chemistry Exam Grades
…starts in Fall 2012. If I am accepted, O.chem is one of 6 courses I must have completed. I cannot fail!… So I can be competitive with other schools, I…
Read moreSuccess Stories: How Stu Aced Organic Chemistry
…tests (20% each) and a final (25%). Each of the tests had 5 (out of 100) extra credit points, no extra credit for the quiz, just a hair of extra…
Read moreThe haloform reaction: conversion of methyl ketones to carboxylic acids
Description: Addition of a dihalogen such as iodine, bromine or chlorine to a methyl ketone in the presence of base results in a carboxylic acid and a haloform (such as…
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