Conversion of thioacetals to alkanes using Raney Nickel
Description: Thioacetals can be desulfurized to give alkanes through the use of Raney nickel (“Ra-Ni”) The rest of this page is available to MOC Members only. To get access to…
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Assigning Cahn-Ingold-Prelog (CIP) Priorities (2) – The Method of Dots
…each atom I am comparing, which is why I call this The Method of Dots). Compare each list, atom by atom. The t-butyl (C(CH3)3) group has the highest priority [C,C,C…
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Read moreSuccess Stories: How Corina Got The The “Hard” Professor – And Got An A+ Anyway
Does your school have that one “hard” organic chemistry instructor that most students try to avoid? Today’s success story comes from Corina, a student in Texas who got assigned the…
Read moreNewman Projection of Butane (and Gauche Conformation)
…are said to be “clinal” (+30° to 150° and -30° to -150°). So there are four possibilities; syn-periplanar, anti-periplanar, syn-clinal (+ and -) and anti-clinal (+ and -). We generally…
Read moreStaggered vs Eclipsed Conformations of Ethane
…strain” is an analogy to the twisting force one experiences when you twist a spring or (more commonly) a rubber band – for instance, in a rubber-band driven propeller plane….
Read moreA Gallery of Some Interesting Molecules From Nature
…of pheromone traps as a popular alternative to pesticides. The molecule below is (Z)-9-tricosene, the pheromone that female houseflies release to attract males. This chemical, commercially known as Muscalure, is…
Read more350 Examples of Classic Org 1/Org 2 Reactions From “Organic Syntheses”
…Flickr: https://www.flickr.com/photos/182129490@N06/collections The set of 350 .CDX files can be downloaded here for free, along with an XLS that contains the DOIs. Coll Org Syn Chemdraw (.zip) including XLSX spreadsheet…
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…CP-225,917 . Tetrahedron 2010 66 (1), 368-378. doi: 10.1016/j.tet.2009.10.071 Kim, J.; Ashenhurst, J. A.; Movassaghi, M. ; Total Synthesis of (+)-11,11′-Dideoxyverticillin A. Science 2009 324 (5924), 238-241 doi: 10.1126/science.1170777 Movassaghi,…
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